The macroporous, strongly acidic, high thermally stable canon exchange resin catalysts were synthesized in the steps of polymerization of styrene and divinylbenzene, purifying copolymer, introducing electron withdrawing group, sulfonation and stabilizing active sites. 通过苯乙烯与二乙烯苯聚合、共聚物纯化、引入吸电子基团、磺化、活性基因稳定化过程,合成耐温强酸阳离子交换树脂催化剂。
Substitution of the aromatic hydrogen atom of the Schiff base ligand with electron withdrawing group decreased the amount of the complex encapsulated in the zeolite cavities, but could improve the catalytic activity of the encapsulated complex. 席夫碱芳环上的H被吸电子基团取代后,降低了Y分子筛超笼中封装的钴配合物的量,但能改善催化活性。
The photodegradation experiment showed that the introduction of electron withdrawing group on methane chain would improve the photo-stability of the dye, while electron donating group would decrease the photo-stability. 三种染料与其母核染料的光降解对比试验说明,甲川链上引入吸电子基团使得染料光稳定性提高,而供电子基团则光稳定性下降。
In chapter 2, we designed and synthesized two novel series of organic dyes by incorporating NC-CH2-COOH as electron withdrawing group at the carbonyl positions of QA skeleton. 在第二章中,我们通过在QA骨架的羰基位置引入吸电子基团NC-CH2-COOH设计并合成了两个系列新颖的有机染料。